Heat-resistant, hydrogen-service, and corrosion-resistant flanges for refineries, chemical plants, and LNG terminals. Full ASME B31.3 compliance, EN 10204 3.1 MTC, and complete material traceability.
Petrochemical and refinery plants process crude oil, natural gas, and chemical feedstocks under a wide range of temperatures (-196°C to 650°C), pressures (vacuum to 300 bar+), and highly corrosive media — from concentrated acids to hydrogen-rich streams.
JIAJI FORGING has supplied flanges and fittings to refinery EPC projects, chemical plant turnarounds, and LNG infrastructure across Asia, the Middle East, and Europe. Our products comply with the most demanding process industry standards including ASME B31.3, PED 2014/68/EU, and NACE MR0175.
Unlike the oil & gas sector which focuses on API wellhead pressure ratings, petrochemical applications demand precise material compatibility with process fluids: sulfuric acid, hydrofluoric acid, amines, chlorides, and high-partial-pressure hydrogen. Material selection is often driven by corrosion allowance calculations to ASME B31.3 Appendix A.
Different process units impose unique demands on flange material, pressure class, and face type
ADU / VDU / Crude Preheat Train
The primary crude distillation unit processes up to 400,000 BPD at temperatures up to 380°C. The vacuum distillation column operates at sub-atmospheric pressures, requiring tight flange sealing to prevent air ingress.
Hydrocracker / Hydrotreater / Reformer
Hydrogen-rich, high-pressure service is among the most demanding for flanges. H₂ partial pressure above 7 bar requires materials qualified against Nelson Curves (API RP 941) to prevent hydrogen embrittlement and HTHA.
DEA / MDEA Absorbers, Claus Tail Gas
Amine treating units remove H₂S and CO₂ from hydrocarbon gas streams. Wet H₂S environments with amines create stress corrosion cracking (SCC) risk for carbon steel; austenitic stainless or duplex are preferred.
LNG Terminals, ASU, NGL Fractionation
Liquefied natural gas at -162°C imposes severe toughness demands on flange materials. Charpy impact testing at -196°C is standard for austenitic grades; special attention to bolting material at low temperature is required.
HF Alkylation, H₂SO₄ Alkylation, Acid Plants
Hydrofluoric acid alkylation units require Monel 400 for HF resistance. Sulfuric acid plants operate with concentrated H₂SO₄ (95–98%) at temperatures up to 450°C in the SO₃ converter.
Steam Crackers, Quench Towers, Compression
Steam cracker furnaces operate at 850–900°C with mixed steam/hydrocarbon feed. The quench section involves rapid cooling from 900°C to below 400°C with acidic condensate. Compression trains require fatigue-rated flanges.
Material selection for petrochemical flanges is driven by process fluid chemistry, temperature, and relevant design codes
ASTM A182 F316L / EN 1.4404 / 1.4571
316Ti (1.4571) for sensitization-prone high-temp service
ASTM A182 F51 / F53 (EN 1.4462 / 1.4410)
2507 preferred for seawater cooling, offshore utilities
ASTM A182 F321H / F347H (EN 1.4541 / 1.4550)
H grade (high carbon) for elevated temperature creep strength
Alloy N10276 (EN 2.4819)
Hastelloy B3 (N10665) for HCl/reducing acid service
Alloy N04400 (EN NiCu30Fe)
Monel K500 for higher strength HF service (valve spindles)
ASTM A182 F304L / F316L (EN 1.4307 / 1.4404)
Min. Charpy at -196°C: 27 J avg / 20 J individual
| EN Designation | Mat. No. | ASTM Grade | Petrochemical Application |
|---|---|---|---|
| X2CrNiMo17-12-2 | 1.4404 | 316L | General chemical service, welds, ADU overhead |
| X6CrNiMoTi17-12-2 | 1.4571 | 316Ti | Naphthenic acid, high-temp process piping |
| X6CrNiTi18-10 | 1.4541 | 321H | Refinery furnace outlets, sensitization protection |
| X6CrNiNb18-10 | 1.4550 | 347H | High-temp steam cracker outlets, quench headers |
| X2CrNiMoN22-5-3 | 1.4462 | F51 (2205) | Sour gas, H₂S + chlorides, amine units |
| X2CrNiMoN25-7-4 | 1.4410 | F53 (2507) | Aggressive chloride, seawater cooling, offshore |
| NiMo16Cr15W | 2.4819 | Hastelloy C276 | Wet SO₂, mixed acids, FGD systems |
| NiCu30Fe | 2.4360 | Monel 400 | HF alkylation, seawater, caustic |
JIAJI FORGING products are manufactured and documented to meet the standards demanded by EPC contractors and plant operators
Process Piping Code. The dominant standard for refinery and chemical plant piping design and fabrication worldwide.
Pipe Flanges and Flanged Fittings, NPS 1/2 to 60". Classes 150–2500 LB. Dimensional and pressure-temperature rating standard.
EU Pressure Equipment Directive. CE marking available for European refinery and chemical plant projects.
Quality Management System. Documented process control from raw material receipt through final inspection and dispatch.
Sour Service Qualification. Materials tested and approved for H₂S-containing environments in refinery and gas treatment units.
Material Test Certificates. Type 3.1 (mill) or 3.2 (independent notified body) certification supplied with every order.
Nelson Curves for hydrogen service. Flange materials selected to avoid HTHA (High Temperature Hydrogen Attack) in hydroprocessing units.
Cryogenic Valve and Equipment Testing. Required for LNG terminal, ASU, and cryogenic separation plant flanges.
ASME B31.3 and ASME B16.5 specify several face types for different service conditions:
For cryogenic service (LNG), RTJ or double-jacketed spiral-wound gaskets in RTJ grooves are preferred to maintain sealing integrity during thermal cycling.
API RP 941 (Nelson Curves) defines the boundary conditions above which carbon and low-alloy steels are susceptible to HTHA (High Temperature Hydrogen Attack — irreversible decarburization and fissuring). Selection process:
Note: Austenitic stainless steels (316, 321H, 347H) are not subject to HTHA and are used in hot H₂ piping above the Nelson Curve boundaries for alloy steels.
LNG service flanges require special qualification beyond standard mechanical testing:
All test records are traceable to heat / lot number and supplied as part of the EN 10204 3.1 documentation package.
Polythionic Acid Stress Corrosion Cracking (PTA-SCC) is a form of intergranular cracking that can occur in sensitized austenitic stainless steel exposed to polythionic acids (H₂SₓO₆) during shutdown and maintenance. The mechanism:
JIAJI recommends F347H or F321H flanges for all refinery furnace outlet and high-temperature piping applications where sensitization is a risk. Per ASTM A262 Practice E / ASTM A193/A194 bolt material requirements for polythionic acid service.
Yes. JIAJI FORGING manufactures forged flanges in Hastelloy C276 (UNS N10276 / EN 2.4819) as both ASME B16.5 and EN 1092-1 configurations:
Typical applications include flue gas desulfurization (FGD), wet SO₂ scrubbers, chloride-containing chemical reactors, and organic acid service in specialty chemical plants.
For European projects under the Pressure Equipment Directive (PED 2014/68/EU), our standard documentation package includes:
Additional documentation per Shell DEP, BP GIS, or Total GS standards available on request. We work with third-party inspection agencies (Bureau Veritas, Lloyd's, SGS, TÜV) as required by project specifications.
The most commonly specified flange and fitting types for refinery and chemical plant projects
Standard for high-temp, high-pressure process units (Class 600–2500 LB)
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Furnace outlet headers, high-temperature creep service (F347H / F91)
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Maintenance isolation, pressure vessel nozzle closures, hydrostatic testing
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Positive isolation for turnaround maintenance, decommissioning, and vessel entry
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